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When a planet passes in front of its parent star, part of the starlight passes through the planet's atmosphere and contains information about the constituents of the atmosphere, providing vital information about the planet itself. This is called a transmission spectrum and even though astronomers can't use exactly the same method to look at the Earth's atmosphere, they were able to gain a spectrum of our planet by observing light reflected from the Moon towards the Earth during a lunar eclipse. This is the first time the transmission spectrum of the Earth has been measured.
Originally quoted from Freeman Dyson "I would say the strategy in looking for life in the universe [should be] to look for what's detectable, not what's probable."