ScienceDaily.com
Possible Mechanism For Creating 'Handedness' In Biological Molecules
Scientists at the U.S. Department of Energy's Argonne National Laboratory have discovered a way to induce this handedness in pre-biological molecules.
"Understanding how the molecules necessary for life originated is one of the most basic scientific questions in biochemistry," Argonne chemist Richard Rosenberg said. "Chirality plays a fundamental role in biological processes and researchers have been trying to discover the mechanisms that led to this property for years."
Rosenberg used X-rays from the Advanced Photon Source to bombard chiral molecules adsorbed on a magnetic substrate and x-ray photoelectron spectroscopy to track changes in the molecular bonds.
He found that changing the magnetization direction in relation to the high-intensity X-ray beam created an excess of one chirality over another. Changing the magnetization direction reverses the spin polarization of the secondary, or low-energy, electrons emitted from the substance.
Iron is a common element and is magnetic in many form and ionizing radiation and magnetic fields are prevalent throughout the universe.
Based on the Argonne results, it is conceivable that chirality could have been introduced by irradiation of molecules as they traveled through the universe while adsorbed on a magnetized substrate in a dust cloud, meteor, comet or on a primitive planet.
"Our study shows that spin-polarized secondary electrons interacting with chiral molecules could produce a significant excess of a given chirality in pre-biological molecules," Rosenberg said.
A paper on Rosenberg's work can be seen in a recent issue of Physical Review Letters.
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The paper can be found through here: Chiral-selective chemistry induced by spin-polarized secondary electrons from a magnetic substrate
Abstract:
Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439, USA.
We demonstrate for the first time that low-energy spin-polarized secondary electrons, produced by irradiation of a magnetic substrate, can induce chiral-selective chemistry. Our approach was to perform detailed measurements of the reaction rate for x-ray induced, secondary electron photolysis of a model chiral compound, (R)- or (S)-2-butanol, adsorbed on a magnetized Permalloy substrate. The results showed that there is an enhancement of approximately 10% in the rate of CO bond cleavage that depends on the chirality of the molecule and the spin polarization of the substrate secondary electrons.
PMID: 18999792 [PubMed - in process]
Not sure if you're still around Zip, or still following this stuff... Just an FYI for you or anyone else whom might be interested.


