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Ozone reacts directly with some hydrocarbons such as aldehydes and thus begins their removal from the air, but the products are themselves key components of smog. Ozone photolysis by UV light leads to production of the hydroxyl radical OH and this plays a part in the removal of hydrocarbons from the air, but is also the first step in the creation of components of smog such as peroxyacyl nitrates which can be powerful eye irritants.
Certain examples of cities with elevated ozone readings are Houston, Texas, and Mexico City, Mexico. Houston has a reading of around 41 ppb, while Mexico City is far more hazardous, with a reading of about 125 ppb.[19]
en.wikipedia.org...
Enhancements in ozone were observed between about 3 and 10 km altitude within an electrically active storm in central New Mexico. Measurements from satellite sensors and ground-based radar show cloud top pressures between 300 and 150 mb in the vicinity of an ozonesonde launched from Socorro, NM, and heavy precipitation with radar reflectivities exceeding 50 dBZ. www.agu.org...