Originally posted by bsbray11
reply to post by iSunTzu
You obviously do not understand chemistry yourself.
The idea that nanoparticles create a more energetic reaction is NOT something Prof. Jones just made up, it's a basic and obvious fact for anyone who understands chemistry. It's not related to a chemical equation, either, but because of the fact that decreasing the particle size increases the amount of actual surface area that makes contact between the particles.
From a DoD-sponsored magazine:
ammtiac.alionscience.com...
Learn chemistry yourself before you accuse Ph.D. physicists of not knowing it.
“Nanostructured composites are multicomponent materials in which at least one of the component phases has one or more dimensions (length, width, or thickness) in the nanometer size range, defined as 1 to 100 nm. Energetic nanocomposites are a class of material that have both a fuel and oxidizer component intimately mixed and where at least one of the component phases meets the size definition. A sol-gel derived pyrotechnic is an example of an energetic nanocomposite, in which metal-oxide nanoparticles react with metals or other fuels in very exothermic reactions. The fuel resides within the pores of the solid matrix while the oxidizer comprises at least a portion of the skeletal matrix.” “As an example, energetic nanocomposites of Fex0y and metallic aluminum are easily synthesized. The compositions are stable, safe and can be readily ignited”[ [19]
“This sol-gel method allows for the addition of insoluble materials (e.g., metals or polymers) to the viscous sol, just before gelation, to producea uniformly distributed and energetic nanocompositeupon gelation. Al metal (as a fine powder,~6μm diameter) was added to some FexOygel syntheses just before gelation to produceFexOy /Al(s) pyrotechnic nanocomposites….These nanocomposites were subsequently processed to make both a xerogel and aerogel of the material…. The pyrotechnic nanocomposite can be ignited using a propane torch” [19].
[19]Gash AE, Simpson RL, Tillotson TM, Satcher JH, Hrubesh LW. Making nanostructured pyrotechnics in a beaker. pre-print UCRL-JC-137593, Lawrence
Livermore National Laboratory: Livermore, Ca; April 10, 2000. [Accessed February 7, 2009]. Available from: www.osti.gov...
posted by SPreston
But allegedly fine particle nano-thermite creates far more energy than ordinary thermite, ...
posted by iSunTzu
Please show us the chemistry equation showing more energy for a chemical reaction because you say it has more energy. You can't change chemistry with nano-thermite mubo jumbo talk. It is thermite or it is not thermite and you can't change chemistry because you say there is more heat per pound because you wish it to be so because you think a failed paper of Jones says so.
I will wait for you to post the formula and how you got more energy from a reaction. How do you and Jones change reality to get more energy out of a pound of thermite? This will be good.
posted by bsbray11
reply to post by iSunTzu
You obviously do not understand chemistry yourself.
The idea that nanoparticles create a more energetic reaction is NOT something Prof. Jones just made up, it's a basic and obvious fact for anyone who understands chemistry. It's not related to a chemical equation, either, but because of the fact that decreasing the particle size increases the amount of actual surface area that makes contact between the particles.
From a DoD-sponsored magazine:
ammtiac.alionscience.com...
Learn chemistry yourself before you accuse Ph.D. physicists of not knowing it.
Originally posted by SPreston
reply to post by pteridine
Oh? So you are guaranteeing that the US Military Weaponry Division is full of it and knows nothing while you know everything?
Originally posted by pteridine
Yes, but the total heat released is about the same for nano and non-nano. The only difference is the inefficiency in the reactions with larger particles. There is no magic to the thermodynamics. If you would like to melt beams, a thin coating of paint won't do it. You still need the joules produced by the reaction.
In any case, there is no physical evidence of thermite.